|
|
5,6,7,8-tetrahydromethanopterin + a_[methyl-Co(III)_corrinoid_Fe-S_protein] <=> 5-Methyl-5,6,7,8-tetrahydromethanopterin + [Co(I)_corrinoid_Fe-S_protein] + H+
|
2.1.1.258
5-methyltetrahydrofolate---corrinoid/iron-sulfur protein Co-methyltransferase
|
–
|
| |
MetaCyc:
RXN-17760
|
|
|
|
CO + H2O + oxidized_ferredoxin <=> CO2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+
|
1.2.7.4
anaerobic carbon monoxide dehydrogenase
|
–
|
| |
BRENDA:
BR36793
KEGG:
R07157
MetaCyc:
1.2.7.4-RXN
|
|
|
|
oxidized_ferredoxin + formylmethanofuran + H2O <=> reduced_ferredoxin_[iron-sulfur]_cluster + methanofuran + CO2 + H+
|
1.2.7.12
formylmethanofuran dehydrogenase
|
–
|
| |
BRENDA:
BR1152;
BS413330;
BS438336
KEGG:
R03015;
R11743
MetaCyc:
FORMYLMETHANOFURAN-DEHYDROGENASE-RXN
|
|
|
|
5,10-methenyl-5,6,7,8-tetrahydromethanopterin + H2O <=> H+ + 5-formyl-5,6,7,8-tetrahydromethanopterin
|
3.5.4.27
methenyltetrahydromethanopterin cyclohydrolase
|
–
|
| |
BRENDA:
BR26119
KEGG:
R03464
MetaCyc:
3.5.4.27-RXN
|
|
|
|
5,6,7,8-tetrahydromethanopterin + formylmethanofuran + H+ <=> 5-formyl-5,6,7,8-tetrahydromethanopterin + methanofuran
|
2.3.1.101
formylmethanofuran---tetrahydromethanopterin N-formyltransferase
|
–
|
| |
BRENDA:
BR43965
KEGG:
R03390
MetaCyc:
2.3.1.101-RXN
|
|
|
|
acetyl-CoA + [Co(I)_corrinoid_Fe-S_protein] + H+ <=> CO + a_[methyl-Co(III)_corrinoid_Fe-S_protein] + CoA
|
2.3.1.169
CO-methylating acetyl-CoA synthase
|
–
|
| |
BRENDA:
BR48047
MetaCyc:
ACETYLSYNCLTH-RXN
|
|
|
|
5,10-methenyl-5,6,7,8-tetrahydromethanopterin + H2 <=> 5,10-methylenetetrahydromethanopterin + H+
|
1.12.98.2
5,10-methenyltetrahydromethanopterin hydrogenase
1.12.99.6
hydrogenase (acceptor)
|
–
–
|
| |
BRENDA:
BR37005
KEGG:
R04455
MetaCyc:
H2-METHYLENE-THMPT-DEHYDRO-RXN
|
|
|
|
5-Methyl-5,6,7,8-tetrahydromethanopterin + coenzyme_F420 <=> 5,10-methylenetetrahydromethanopterin + reduced_coenzyme_F420
|
1.5.98.2
5,10-methylenetetrahydromethanopterin reductase
|
–
|
| |
BRENDA:
BR29453
KEGG:
R04464
MetaCyc:
METHELENE-THMPT-OXI-RXN
SABIO-RK:
4147
|
|
